Processes in Microsoft 365 for setting up Office apps, redeeming product keys, and activating licenses.
If you are already a member of a family group and sharing a subscription, you usually don't have to join again.
Which steps did you try, specifically? I would suggest that you check with the family member whose account pays for the subscription that you are still listed as a family member who is sharing the 365 Family subscription.
You can also verify in your own account, via https://account.microsoft.com , that someone is sharing the Family subscription with you.
If the correct version of Office is installed on your PC, you should be able to start an Office app and then sign in to activate. For more, read the article at https://support.microsoft.com/en-us/accounts-billing/subscriptions/sign-in-to-microsoft-365 .
P.S. Microsoft offers very limited phone support for consumer (home use) products. There is a chat that you can try, if everything else fails. You, or the person who is paying for the subscription, should go to https://support.microsoft.com/contactus .