協助使用者管理訂閱、帳戶設定和帳單資訊的 Microsoft 365 功能。
Hello,
There is no need for a product key in order to activate Microsoft 365 apps, you just need to sign in with the account where the office license associated with.
To further check on which is the correct account the Office license associated to, just to go to account.microsoft.com/services > then from the subscription, you can see there if the subscription is active on the account you signed in. If its not there, then try the other account to check.