Hi,
- Open Outlook → File → Account Settings → Account Settings.
- Select your email account → Change → More Settings.
- Under Advanced, verify:
- IMAP: 143
- SMTP: 25
- Check the encryption/SSL/TLS settings specified by your mail provider. Do not enable SSL blindly if the provider specifically requires an unencrypted connection or STARTTLS.
Also, please let me know where do you see that SMTP 25 is blocked, a screenshot will be awesome!