Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
Hello,
Since you purchased Microsoft 365 Apps for Business directly from Microsoft but cannot access the associated subscription or admin center, I would recommend approaching this as a subscription ownership and account-access issue rather than an Office activation issue alone.
Here are a few steps worth trying:
1. Verify the purchase and associated account
Sign in to the Microsoft account used during checkout and review your order history:
https://account.microsoft.com/billing/orders
Check whether the purchase appears there and whether the confirmation email identifies the account or subscription associated with the transaction.
2. Check whether the business subscription is associated with a different tenant
A business subscription can be associated with an organizational Microsoft Entra tenant. Successfully signing in with a personal or business email address does not necessarily mean that either account has the required administrative role.
Try checking the organization sign-in through:
https://myaccount.microsoft.com/
3. Contact Microsoft through the purchase and billing support channel
Since you purchased directly from Microsoft and cannot access the Microsoft 365 admin center, try Microsoft's official business support contact page:
https://support.microsoft.com/contactus
Explain that:
You have a paid Microsoft 365 Apps for Business subscription.
You cannot identify or access the administrator account associated with the purchase.
The admin center returns error 100014.
You need assistance verifying the purchase and identifying the associated tenant.
Ask whether the case can be routed to the appropriate Microsoft 365 business subscription or Data Protection team if tenant ownership verification is required.
4. Keep your purchase evidence available
Have your Microsoft order number, purchase confirmation, transaction date, and payment evidence ready. Share these only through an official Microsoft support channel, not in a public forum.
One important distinction: Microsoft 365 Apps for Business is not the same subscription as Microsoft 365 Business Standard or Business Premium. The exact subscription SKU and purchase record may help support identify the correct account and tenant.
If Microsoft cannot restore access or provide the purchased entitlement, ask the billing team to review your refund eligibility.
I would avoid creating another tenant or purchasing another subscription until Microsoft has investigated the original order.