Microsoft 365 features that help users manage their subscriptions, account settings, and billing information.
To better understand the issue, could you please provide the following details?
- What type of device are you using (Windows PC, Mac, iPhone/iPad, or Android)?
- Which Microsoft service or application are you trying to sign in to when this occurs (for example, Microsoft 365, Outlook, Edge, or another Microsoft service)?
- Is this the first time you are signing in to the new Business Account, or have you already signed in to it successfully before?
- Do you recall where you originally set up the passkey for the old Personal Microsoft account, such as on your Windows device, phone, Microsoft Authenticator, or another password manager?
- Which email address do you enter, and when the passkey prompt appears, does it automatically sign you in to the old Personal account, or does it simply offer that account as an option?
- Could you please provide a screenshot of the sign-in/passkey prompt you are seeing? Please remove or hide any personal information, passwords, security codes, or other sensitive details before sharing the screenshot.
Regarding Microsoft Authenticator, it is Microsoft's mobile authentication app available for iPhone and Android devices. It can be used to approve sign-in requests, generate verification codes for multi-factor authentication (MFA), and support passwordless sign-in. In some scenarios, it can also be used to store passkeys.
About Microsoft Authenticator | Microsoft Support
However, passkeys may also be stored in other locations, such as Windows Hello, Apple iCloud Keychain, Google Password Manager, or another credential manager, depending on how they were originally set up.
For more information about passkeys and how they can be managed, you may find the following Microsoft Support articles helpful:
- What are passkeys and why they matter | Microsoft Support
- Manage your saved passkeys | Microsoft Support
This information will help provide more accurate guidance for your scenario.